I have an intelligent split charge relay to charge the leisure battery on my camper, very easy to wire up and works a treat. it just connects the two batteries in parallel as soon as it sees 13.5 ish volts (alternator charging) and cuts out within 30 seconds or so when the voltage drops below a set trigger point. The only down side to any split charge system is that if your second battery has been run very low then it will be force fed everything that your alternator can spare when it first connects as there is no limiter to keep it down to lower (kinder) current. You just need to bear that in mind when selecting your second battery as some gel types cannot take high charge or discharge rates very well.
On my camper, if the leisure battery is really low then the initial surge can peak at over 40 amps charge rate, it only lasts a few seconds and then drops rapidly to a far more reasonable figure, however that is to charge a 110ah leisure battery.
if it is just a spare power source for charging phones and sat navs etc then a power monkey or similar may prove a better (and much lighter) option.