I used to put a tank of Shell V-Power through my old 1150GS as the detergent additives helped keep the inside hot bits clean and working properly, until...
Going to the Isle of Wight for a weekend, filled up with V-Power and went M25/A3 at a fair rate with the dearly beloved and luggage. All was well until the bike turned into a jack-hammer at about 85 in the outside lane part way past a car. Having got to the hard shoulder with out hitting anything, being rescued by the RAC, and getting taken to my preferred dealer they found: a burnt out exhaust valve, snapped cam-chain tensioner, big gouges in the cam-chain guide. If it wasn't for having a good and sympathetic mechanic that lot would have cost me in excess of £1700 !!
I was running the 1150 with a full Remus system with not 'cat'; this makes the bike run much better and gave better mpg as the bike ran slightly leaner. V-Power gives better mpg because it runs slightly leaner...
Nearly 65 miles at speed fully loaded results in the above.
So if you are running an non-standard exhaust I'd be a bit wary about using anything other than recommended.
I'm sticking to the 95ron with the 800GS, which also has a Remus system and no 'cat'.
SuperTed