Are we saying that the centrifugal force is enough to distort the rubber seal around the post and this is where the air leaks from or is the suggestion the the force is enough to force the valve spring down letting the air out ? If the second,no dust cap fitted would let the air out, but if a dust cap was fitted the forces acting on that (especially if a heaver type - metal) may be enough to seal the the top of the stem (probably aided by the force from it being tightened) and help prevent the loss of air.
Can someone with a rolling road and a high speed camera please carry out an experiment and let us know at what speed we need to worry.....
Cheers